| 1. Ronde | 19.08.1966 | Toulouse FC | - | AS Saint-Étienne | 0:2 | ||||
| 2. Ronde | 27.08.1966 | AS Saint-Étienne | - | Olympique Marseille | 2:0 | ||||
| 3. Ronde | 31.08.1966 | OGC Nice | - | AS Saint-Étienne | 1:2 | ||||
| 4. Ronde | 03.09.1966 | AS Saint-Étienne | - | Girondins Bordeaux | 1:1 | ||||
| 5. Ronde | 10.09.1966 | RC Strasbourg | - | AS Saint-Étienne | 2:1 | ||||
| 6. Ronde | 14.09.1966 | AS Saint-Étienne | - | FC Rouen 1899 | 3:0 | ||||
| 7. Ronde | 18.09.1966 | Stade Rennais | - | AS Saint-Étienne | 1:1 | ||||
| 8. Ronde | 23.09.1966 | AS Saint-Étienne | - | CS Sedan | 1:0 | ||||
| 9. Ronde | 02.10.1966 | Olympique Lyonnais | - | AS Saint-Étienne | 3:0 | ||||
| 10. Ronde | 09.10.1966 | AS Saint-Étienne | - | FC Nantes | 3:3 | ||||
| 11. Ronde | 12.10.1966 | RC Lens | - | AS Saint-Étienne | 2:0 | ||||
| 12. Ronde | 15.10.1966 | AS Saint-Étienne | - | US Valenciennes-Anzin | 3:1 | ||||
| 13. Ronde | 30.10.1966 | Stade de Paris FC | - | AS Saint-Étienne | 1:1 | ||||
| 14. Ronde | 01.11.1966 | AS Saint-Étienne | - | FC Sochaux | 1:0 | ||||
| 16. Ronde | 13.11.1966 | AS Saint-Étienne | - | Nîmes Olympique | 3:1 | ||||
| 17. Ronde | 20.11.1966 | AS Saint-Étienne | - | Lille OSC | 4:1 | ||||
| 15. Ronde | 29.11.1966 | AS Monaco | - | AS Saint-Étienne | 1:0 |
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