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| U | RB Leipzig | - | Liverpool FC | 0:2 (0:0) | ||
| R | Liverpool FC | - | RB Leipzig | 2:0 (0:0) | ||
| U: 16.02.2021 21:00 | R: 10.03.2021 21:00 | Winnaars: Liverpool FC | ||||
| U | FC Barcelona | - | Paris Saint-Germain | 1:4 (1:1) | ||
| R | Paris Saint-Germain | - | FC Barcelona | 1:1 (1:1) | ||
| U: 16.02.2021 21:00 | R: 10.03.2021 21:00 | Winnaars: Paris Saint-Germain | ||||
| U | FC Porto | - | Juventus | 2:1 (1:0) | ||
| R | Juventus | - | FC Porto | 3:2 (0:1, 2:1) n.v. | ||
| U: 17.02.2021 21:00 | R: 09.03.2021 21:00 | Winnaars: FC Porto | ||||
| U | Sevilla FC | - | Borussia Dortmund | 2:3 (1:3) | ||
| R | Borussia Dortmund | - | Sevilla FC | 2:2 (1:0) | ||
| U: 17.02.2021 21:00 | R: 09.03.2021 21:00 | Winnaars: Borussia Dortmund | ||||
| U | Lazio | - | Bayern München | 1:4 (0:3) | ||
| R | Bayern München | - | Lazio | 2:1 (1:0) | ||
| U: 23.02.2021 21:00 | R: 17.03.2021 21:00 | Winnaars: Bayern München | ||||
| U | Atlético Madrid | - | Chelsea FC | 0:1 (0:0) | ||
| R | Chelsea FC | - | Atlético Madrid | 2:0 (1:0) | ||
| U: 23.02.2021 21:00 | R: 17.03.2021 21:00 | Winnaars: Chelsea FC | ||||
| U | Bor. Mönchengladbach | - | Manchester City | 0:2 (0:1) | ||
| R | Manchester City | - | Bor. Mönchengladbach | 2:0 (2:0) | ||
| U: 24.02.2021 21:00 | R: 16.03.2021 21:00 | Winnaars: Manchester City | ||||
| U | Atalanta | - | Real Madrid | 0:1 (0:0) | ||
| R | Real Madrid | - | Atalanta | 3:1 (1:0) | ||
| U: 24.02.2021 21:00 | R: 16.03.2021 21:00 | Winnaars: Real Madrid | ||||
