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| U | CD Dénia | - | Sevilla FC | 1:1 (0:0) | ||
| R | Sevilla FC | - | CD Dénia | 4:3 (2:0) | ||
| U: 13.11.2007 21:00 | R: 02.01.2008 21:00 | Winnaars: Sevilla FC | ||||
| U | CD Alcoyano | - | FC Barcelona | 0:3 (0:1) | ||
| R | FC Barcelona | - | CD Alcoyano | 2:2 (2:0) | ||
| U: 13.11.2007 21:00 | R: 02.01.2008 18:00 | Winnaars: FC Barcelona | ||||
| U | Hércules CF | - | Athletic Club | 2:2 (2:0) | ||
| R | Athletic Club | - | Hércules CF | 2:0 (0:0) | ||
| U: 13.11.2007 21:30 | R: 02.01.2008 22:00 | Winnaars: Athletic Club | ||||
| U | Real Valladolid | - | Real Murcia | 1:1 (0:0) | ||
| R | Real Murcia | - | Real Valladolid | 2:3 (1:1) | ||
| U: 14.11.2007 20:00 | R: 02.01.2008 20:45 | Winnaars: Real Valladolid | ||||
| U | Pontevedra CF | - | Real Zaragoza | 1:0 (0:0) | ||
| R | Real Zaragoza | - | Pontevedra CF | 3:1 (0:1) | ||
| U: 14.11.2007 20:30 | R: 03.01.2008 21:00 | Winnaars: Real Zaragoza | ||||
| U | Málaga CF | - | Racing Santander | 0:0 (0:0) | ||
| R | Racing Santander | - | Málaga CF | 2:0 (2:0) | ||
| U: 14.11.2007 21:00 | R: 02.01.2008 21:00 | Winnaars: Racing Santander | ||||
| U | Xerez CD | - | Recreativo Huelva | 0:1 (0:0) | ||
| R | Recreativo Huelva | - | Xerez CD | 1:1 (1:1) | ||
| U: 14.11.2007 21:00 | R: 02.01.2008 20:45 | Winnaars: Recreativo Huelva | ||||
| U | Levante UD | - | UD Almería | 2:1 (2:1) | ||
| R | UD Almería | - | Levante UD | 1:1 (0:0) | ||
| U: 14.11.2007 21:30 | R: 03.01.2008 20:30 | Winnaars: Levante UD | ||||
| U | UD Las Palmas | - | Villarreal CF | 2:4 (1:2) | ||
| R | Villarreal CF | - | UD Las Palmas | 2:1 (0:1) | ||
| U: 14.11.2007 22:00 | R: 02.01.2008 20:00 | Winnaars: Villarreal CF | ||||
| U | Burgos CF | - | Getafe CF | 0:1 (0:1) | ||
| R | Getafe CF | - | Burgos CF | 4:1 (1:0) | ||
| U: 12.12.2007 20:45 | R: 02.01.2008 17:00 | Winnaars: Getafe CF | ||||
| U | Granada 74 CF | - | Atlético Madrid | 1:2 (0:1) | ||
| R | Atlético Madrid | - | Granada 74 CF | 1:1 (0:0) | ||
| U: 12.12.2007 21:00 | R: 02.01.2008 21:00 | Winnaars: Atlético Madrid | ||||
| U | Elche CF | - | Real Betis | 1:1 (1:0) | ||
| R | Real Betis | - | Elche CF | 3:0 (1:0) | ||
| U: 12.12.2007 21:00 | R: 02.01.2008 21:00 | Winnaars: Real Betis | ||||
| U | CA Osasuna | - | RCD Mallorca | 2:0 (2:0) | ||
| R | RCD Mallorca | - | CA Osasuna | 4:0 (0:0) | ||
| U: 12.12.2007 21:30 | R: 02.01.2008 21:30 | Winnaars: RCD Mallorca | ||||
| U | Alicante CF | - | Real Madrid | 1:1 (0:0) | ||
| R | Real Madrid | - | Alicante CF | 2:1 (1:0) | ||
| U: 19.12.2007 20:45 | R: 02.01.2008 20:00 | Winnaars: Real Madrid | ||||
| U | Espanyol | - | Deportivo La Coruña | 1:1 (0:1) | ||
| R | Deportivo La Coruña | - | Espanyol | 1:2 (0:1, 1:1) n.v. | ||
| U: 19.12.2007 20:45 | R: 02.01.2008 21:00 | Winnaars: Espanyol | ||||
| U | Real Unión | - | Valencia CF | 1:2 (1:0) | ||
| R | Valencia CF | - | Real Unión | 3:0 (0:0) | ||
| U: 19.12.2007 21:30 | R: 02.01.2008 22:00 | Winnaars: Valencia CF | ||||
