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| U | Valencia CF | - | Atlético Madrid | 1:1 (0:0) | ||
| R | Atlético Madrid | - | Valencia CF | 2:0 (0:0) | ||
| U: 07.01.2014 22:00 | R: 14.01.2014 21:30 | Winnaars: Atlético Madrid | ||||
| U | AD Alcorcón | - | Espanyol | 1:0 (0:0) | ||
| R | Espanyol | - | AD Alcorcón | 4:2 (2:1) | ||
| U: 08.01.2014 20:00 | R: 15.01.2014 19:30 | Winnaars: Espanyol | ||||
| U | Real Betis | - | Athletic Club | 1:0 (1:0) | ||
| R | Athletic Club | - | Real Betis | 2:0 (1:0) | ||
| U: 08.01.2014 20:00 | R: 15.01.2014 19:30 | Winnaars: Athletic Club | ||||
| U | FC Barcelona | - | Getafe CF | 4:0 (1:0) | ||
| R | Getafe CF | - | FC Barcelona | 0:2 (0:1) | ||
| U: 08.01.2014 22:00 | R: 16.01.2014 22:00 | Winnaars: FC Barcelona | ||||
| U | Racing Santander | - | UD Almería | 1:1 (0:1) | ||
| R | UD Almería | - | Racing Santander | 0:2 (0:0) | ||
| U: 08.01.2014 22:00 | R: 14.01.2014 19:30 | Winnaars: Racing Santander | ||||
| U | Real Sociedad | - | Villarreal CF | 0:0 (0:0) | ||
| R | Villarreal CF | - | Real Sociedad | 0:1 (0:1) | ||
| U: 09.01.2014 19:30 | R: 16.01.2014 20:00 | Winnaars: Real Sociedad | ||||
| U | Rayo Vallecano | - | Levante UD | 0:0 (0:0) | ||
| R | Levante UD | - | Rayo Vallecano | 1:0 (1:0) | ||
| U: 09.01.2014 21:30 | R: 15.01.2014 21:30 | Winnaars: Levante UD | ||||
| U | Real Madrid | - | CA Osasuna | 2:0 (1:0) | ||
| R | CA Osasuna | - | Real Madrid | 0:2 (0:1) | ||
| U: 09.01.2014 21:30 | R: 15.01.2014 21:30 | Winnaars: Real Madrid | ||||
