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| U | UE Cornellà | - | Real Madrid | 1:4 (1:2) | ||
| R | Real Madrid | - | UE Cornellà | 5:0 (3:0) | ||
| U: 29.10.2014 20:00 | R: 02.12.2014 20:00 | Winnaars: Real Madrid | ||||
| U | CE Sabadell | - | Sevilla FC | 1:6 (0:2) | ||
| R | Sevilla FC | - | CE Sabadell | 5:1 (1:1) | ||
| U: 29.10.2014 22:00 | R: 03.12.2014 20:00 | Winnaars: Sevilla FC | ||||
| U | CD Alcoyano | - | Athletic Club | 1:1 (1:0) | ||
| R | Athletic Club | - | CD Alcoyano | 1:0 (1:0) | ||
| U: 02.12.2014 20:00 | R: 18.12.2014 22:00 | Winnaars: Athletic Club | ||||
| U | Deportivo Alavés | - | Espanyol | 0:2 (0:1) | ||
| R | Espanyol | - | Deportivo Alavés | 1:0 (0:0) | ||
| U: 02.12.2014 20:00 | R: 17.12.2014 20:00 | Winnaars: Espanyol | ||||
| U | UD Las Palmas | - | Celta de Vigo | 2:1 (1:0) | ||
| R | Celta de Vigo | - | UD Las Palmas | 3:1 (1:0) | ||
| U: 02.12.2014 22:00 | R: 16.12.2014 20:00 | Winnaars: Celta de Vigo | ||||
| U | Real Valladolid | - | Elche CF | 0:0 (0:0) | ||
| R | Elche CF | - | Real Valladolid | 1:0 (1:0) | ||
| U: 02.12.2014 22:00 | R: 18.12.2014 20:00 | Winnaars: Elche CF | ||||
| U | CE L'Hospitalet | - | Atlético Madrid | 0:3 (0:0) | ||
| R | Atlético Madrid | - | CE L'Hospitalet | 2:2 (1:0) | ||
| U: 03.12.2014 20:00 | R: 18.12.2014 20:00 | Winnaars: Atlético Madrid | ||||
| U | Deportivo La Coruña | - | Málaga CF | 1:1 (0:1) | ||
| R | Málaga CF | - | Deportivo La Coruña | 4:1 (0:0) | ||
| U: 03.12.2014 20:00 | R: 18.12.2014 22:00 | Winnaars: Málaga CF | ||||
| U | SD Huesca | - | FC Barcelona | 0:4 (0:3) | ||
| R | FC Barcelona | - | SD Huesca | 8:1 (5:0) | ||
| U: 03.12.2014 22:00 | R: 16.12.2014 22:00 | Winnaars: FC Barcelona | ||||
| U | Granada CF | - | Córdoba CF | 1:0 (1:0) | ||
| R | Córdoba CF | - | Granada CF | 1:1 (1:0) | ||
| U: 03.12.2014 22:00 | R: 17.12.2014 22:00 | Winnaars: Granada CF | ||||
| U | Cádiz CF | - | Villarreal CF | 1:2 (0:2) | ||
| R | Villarreal CF | - | Cádiz CF | 3:0 (0:0) | ||
| U: 04.12.2014 20:00 | R: 17.12.2014 22:00 | Winnaars: Villarreal CF | ||||
| U | Real Oviedo | - | Real Sociedad | 0:0 (0:0) | ||
| R | Real Sociedad | - | Real Oviedo | 2:0 (1:0) | ||
| U: 04.12.2014 20:00 | R: 17.12.2014 22:00 | Winnaars: Real Sociedad | ||||
| U | Rayo Vallecano | - | Valencia CF | 1:2 (1:0) | ||
| R | Valencia CF | - | Rayo Vallecano | 4:4 (1:3) | ||
| U: 04.12.2014 22:00 | R: 16.12.2014 20:00 | Winnaars: Valencia CF | ||||
| U | Albacete | - | Levante UD | 1:1 (1:0) | ||
| R | Levante UD | - | Albacete | 0:0 (0:0) | ||
| U: 05.12.2014 20:00 | R: 17.12.2014 20:00 | Winnaars: Levante UD | ||||
| U | Getafe CF | - | SD Eibar | 3:0 (0:0) | ||
| R | SD Eibar | - | Getafe CF | 1:2 (0:2) | ||
| U: 05.12.2014 20:00 | R: 17.12.2014 20:00 | Winnaars: Getafe CF | ||||
| U | Real Betis | - | UD Almería | 3:4 (0:3) | ||
| R | UD Almería | - | Real Betis | 2:1 (0:0) | ||
| U: 05.12.2014 22:00 | R: 16.12.2014 22:00 | Winnaars: UD Almería | ||||
