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| U | CD Ebro | - | Valencia CF | 1:2 (0:0) | ||
| R | Valencia CF | - | CD Ebro | 1:0 (0:0) | ||
| U: 30.10.2018 19:30 | R: 04.12.2018 19:30 | Winnaars: Valencia CF | ||||
| U | CD Lugo | - | Levante UD | 1:1 (1:0) | ||
| R | Levante UD | - | CD Lugo | 2:0 (0:0) | ||
| U: 30.10.2018 19:30 | R: 06.12.2018 12:00 | Winnaars: Levante UD | ||||
| U | CD Leganés | - | Rayo Vallecano | 2:2 (1:2) | ||
| R | Rayo Vallecano | - | CD Leganés | 0:1 (0:1) | ||
| U: 30.10.2018 20:30 | R: 04.12.2018 20:30 | Winnaars: CD Leganés | ||||
| U | UE Sant Andreu | - | Atlético Madrid | 0:1 (0:1) | ||
| R | Atlético Madrid | - | UE Sant Andreu | 4:0 (0:0) | ||
| U: 30.10.2018 21:30 | R: 05.12.2018 19:30 | Winnaars: Atlético Madrid | ||||
| U | UD Melilla | - | Real Madrid | 0:4 (0:2) | ||
| R | Real Madrid | - | UD Melilla | 6:1 (3:0) | ||
| U: 31.10.2018 19:30 | R: 06.12.2018 16:15 | Winnaars: Real Madrid | ||||
| U | RCD Mallorca | - | Real Valladolid | 1:2 (0:2) | ||
| R | Real Valladolid | - | RCD Mallorca | 2:1 (0:0) | ||
| U: 31.10.2018 20:30 | R: 05.12.2018 21:30 | Winnaars: Real Valladolid | ||||
| U | Córdoba CF | - | Getafe CF | 1:2 (1:1) | ||
| R | Getafe CF | - | Córdoba CF | 5:1 (2:0) | ||
| U: 31.10.2018 20:30 | R: 04.12.2018 19:30 | Winnaars: Getafe CF | ||||
| U | Deportivo Alavés | - | Girona FC | 2:2 (0:1) | ||
| R | Girona FC | - | Deportivo Alavés | 2:1 (0:0) | ||
| U: 31.10.2018 20:30 | R: 05.12.2018 19:30 | Winnaars: Girona FC | ||||
| U | Cultural Leonesa | - | FC Barcelona | 0:1 (0:0) | ||
| R | FC Barcelona | - | Cultural Leonesa | 4:1 (3:0) | ||
| U: 31.10.2018 21:30 | R: 05.12.2018 21:30 | Winnaars: FC Barcelona | ||||
| U | Sporting Gijón | - | SD Eibar | 2:0 (0:0) | ||
| R | SD Eibar | - | Sporting Gijón | 2:2 (0:2) | ||
| U: 01.11.2018 12:00 | R: 06.12.2018 18:30 | Winnaars: Sporting Gijón | ||||
| U | CF Villanovense | - | Sevilla FC | 0:0 (0:0) | ||
| R | Sevilla FC | - | CF Villanovense | 1:0 (0:0) | ||
| U: 01.11.2018 16:15 | R: 05.12.2018 20:30 | Winnaars: Sevilla FC | ||||
| U | Celta de Vigo | - | Real Sociedad | 1:1 (0:0) | ||
| R | Real Sociedad | - | Celta de Vigo | 2:0 (2:0) | ||
| U: 01.11.2018 16:15 | R: 05.12.2018 20:30 | Winnaars: Real Sociedad | ||||
| U | UD Almería | - | Villarreal CF | 3:3 (0:0) | ||
| R | Villarreal CF | - | UD Almería | 8:0 (4:0) | ||
| U: 01.11.2018 18:30 | R: 05.12.2018 20:30 | Winnaars: Villarreal CF | ||||
| U | Cádiz CF | - | Espanyol | 2:1 (2:1) | ||
| R | Espanyol | - | Cádiz CF | 1:0 (0:0) | ||
| U: 01.11.2018 18:30 | R: 04.12.2018 21:30 | Winnaars: Espanyol | ||||
| U | Racing Santander | - | Real Betis | 0:1 (0:1) | ||
| R | Real Betis | - | Racing Santander | 4:0 (1:0) | ||
| U: 01.11.2018 20:45 | R: 06.12.2018 20:45 | Winnaars: Real Betis | ||||
| U | Athletic Club | - | SD Huesca | 4:0 (3:0) | ||
| R | SD Huesca | - | Athletic Club | 0:4 (0:1) | ||
| U: 28.11.2018 20:45 | R: 06.12.2018 18:30 | Winnaars: Athletic Club | ||||
