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| 16.10.1966 | Sporting Gijón | - | Racing Santander | 5:1 | ||
| CD Tenerife | - | CA Osasuna | 1:0 | |||
| Racing Ferrol | - | Celta de Vigo | 0:0 | |||
| Burgos CF | - | CF Calvo Sotelo | 0:0 | |||
| Gimnástica Torrelavega | - | Real Oviedo | 2:1 | |||
| SD Indautxu | - | Rayo Vallecano | 2:1 | |||
| UP Langreo | - | Real Valladolid | 1:1 | |||
| Real Sociedad | - | CD Logroñés | 3:0 | |||
| UE Lleida | - | CD Mestalla | 2:1 | |||
| Cádiz CF | - | CD Castellón | 2:0 | |||
| Levante UD | - | CF Badalona | 2:0 | |||
| Algeciras CF | - | Recreativo Huelva | 1:1 | |||
| CD Málaga | - | Real Murcia | 3:0 | |||
| CE Europa | - | CD Condal | 2:2 | |||
| CA Ceuta | - | RCD Mallorca | 0:0 | |||
| CD Constància | - | Real Betis | 3:1 |
| » Stand | Thuis | uit | Heenronde | Returnronde |
| 1 | |||||||||
| # | Team | GS. | W. | G. | V. | Dp. | Ds. | P. | |
|---|---|---|---|---|---|---|---|---|---|
| 1 |
|
Sporting Gijón | 6 | 4 | 1 | 1 | 13:3 | 10 | 9:3 |
| 2 |
|
Rayo Vallecano | 6 | 4 | 0 | 2 | 14:4 | 10 | 8:4 |
| 3 |
|
CF Calvo Sotelo | 6 | 3 | 2 | 1 | 7:2 | 5 | 8:4 |
| 4 |
|
Racing Santander | 6 | 4 | 0 | 2 | 11:8 | 3 | 8:4 |
| 5 |
|
Racing Ferrol | 6 | 3 | 1 | 2 | 11:4 | 7 | 7:5 |
| 6 |
|
Celta de Vigo | 6 | 3 | 1 | 2 | 8:6 | 2 | 7:5 |
| 7 |
|
Real Sociedad | 6 | 3 | 1 | 2 | 9:9 | 0 | 7:5 |
| 8 |
|
Gimnástica Torrelavega | 6 | 3 | 0 | 3 | 8:12 | -4 | 6:6 |
| 9 |
|
Real Valladolid | 6 | 2 | 1 | 3 | 8:7 | 1 | 5:7 |
| 10 |
|
UP Langreo | 6 | 2 | 1 | 3 | 6:7 | -1 | 5:7 |
| 11 |
|
SD Indautxu | 6 | 2 | 1 | 3 | 4:9 | -5 | 5:7 |
| 12 |
|
Real Oviedo | 6 | 2 | 1 | 3 | 8:9 | -1 | 5:7 |
| 13 |
|
CD Tenerife | 6 | 2 | 1 | 3 | 6:9 | -3 | 5:7 |
| 14 |
|
Burgos CF | 6 | 1 | 2 | 3 | 3:8 | -5 | 4:8 |
| 15 |
|
CD Logroñés | 6 | 2 | 0 | 4 | 4:16 | -12 | 4:8 |
| 16 |
|
CA Osasuna | 6 | 1 | 1 | 4 | 6:13 | -7 | 3:9 |
| 2 | |||||||||
| # | Team | GS. | W. | G. | V. | Dp. | Ds. | P. | |
|---|---|---|---|---|---|---|---|---|---|
| 1 |
|
CD Málaga | 6 | 4 | 2 | 0 | 9:3 | 6 | 10:2 |
|
Levante UD | 6 | 5 | 0 | 1 | 9:3 | 6 | 10:2 | |
| 3 |
|
Real Betis | 6 | 3 | 1 | 2 | 12:6 | 6 | 7:5 |
| 4 |
|
CD Castellón | 6 | 3 | 1 | 2 | 5:4 | 1 | 7:5 |
| 5 |
|
RCD Mallorca | 6 | 2 | 2 | 2 | 6:5 | 1 | 6:6 |
| 6 |
|
Recreativo Huelva | 6 | 2 | 2 | 2 | 5:5 | 0 | 6:6 |
| 7 |
|
CA Ceuta | 6 | 2 | 2 | 2 | 5:6 | -1 | 6:6 |
| 8 |
|
CE Europa | 6 | 2 | 2 | 2 | 5:6 | -1 | 6:6 |
| 9 |
|
CD Constància | 6 | 2 | 1 | 3 | 7:7 | 0 | 5:7 |
| 10 |
|
Algeciras CF | 6 | 1 | 3 | 2 | 6:8 | -2 | 5:7 |
| 11 |
|
Cádiz CF | 6 | 1 | 3 | 2 | 5:7 | -2 | 5:7 |
| 12 |
|
UE Lleida | 6 | 2 | 1 | 3 | 4:6 | -2 | 5:7 |
| 13 |
|
CD Mestalla | 6 | 2 | 1 | 3 | 11:18 | -7 | 5:7 |
| 14 |
|
Real Murcia | 6 | 2 | 1 | 3 | 10:9 | 1 | 5:7 |
| 15 |
|
CD Condal | 6 | 1 | 2 | 3 | 8:10 | -2 | 4:8 |
| 16 |
|
CF Badalona | 6 | 1 | 2 | 3 | 3:7 | -4 | 4:8 |
